Beilstein J. Org. Chem.2012,8, 738–743, doi:10.3762/bjoc.8.83
functionalized with nitroaryl and arylamino groups were synthesized from the bisdioxine diacid dichloride 1,3,5,7-tetra-tert-butyl-2,6,9-trioxabicyclo[3.3.1]nona-3,7-diene-4,8-dicarbonyl dichloride (3).
Keywords: bisdioxine; macrocyclic amines; macrocyclicnitrocompounds; tetraoxaadamantane; Introduction
The
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Graphical Abstract
Scheme 1:
Synthesis of macrocyclic bisdioxine derivatives (R,S-form of 4 and S-form of 5 shown; see Supporting Information File 1 for deta...